Enhanced Up‐Conversion Luminescence in Er3+‐Doped 25GeS2·35Ga2S3·40CsCl Chalcogenide Glass–Ceramics
Identifieur interne : 000583 ( Main/Exploration ); précédent : 000582; suivant : 000584Enhanced Up‐Conversion Luminescence in Er3+‐Doped 25GeS2·35Ga2S3·40CsCl Chalcogenide Glass–Ceramics
Auteurs : Changgui Lin [République populaire de Chine] ; Laurent Calvez [France] ; Zhuobin Li [République populaire de Chine] ; Shixun Dai [République populaire de Chine] ; Haizheng Tao [République populaire de Chine] ; Hongli Ma [France] ; Xianghua Zhang [France] ; Bernard Moine [France] ; Xiujian Zhao [République populaire de Chine]Source :
- Journal of the American Ceramic Society [ 0002-7820 ] ; 2013-03.
English descriptors
- KwdEn :
- Absorption spectrum, Base glass, Chalcogenide, Chalcogenide glass, Chalcogenide glasses, Characteristic temperatures, Chlorine coordination, Crystalline phases, Crystallization, Crystallization process, Fundamental mechanism, Glass matrix, Heat treatment, Heat treatments, Heating rate, Ion, Large amount, Laser, Local structure, Luminescence, Luminescence intensity, Luminescence spectra, Matrix, Maximum phonon energy, Microstructural evolution, Ningbo city, Ningbo university, Phonon, Phonon energy, Phys, Precipitation, Raman, Raman band, Residual, Residual glass matrix, Spectral region, Spectroscopic properties, Transmission spectra, Upconversion luminescence, Zhang.
- Teeft :
- Absorption spectrum, Base glass, Chalcogenide, Chalcogenide glass, Chalcogenide glasses, Characteristic temperatures, Chlorine coordination, Crystalline phases, Crystallization, Crystallization process, Fundamental mechanism, Glass matrix, Heat treatment, Heat treatments, Heating rate, Ion, Large amount, Laser, Local structure, Luminescence, Luminescence intensity, Luminescence spectra, Matrix, Maximum phonon energy, Microstructural evolution, Ningbo city, Ningbo university, Phonon, Phonon energy, Phys, Precipitation, Raman, Raman band, Residual, Residual glass matrix, Spectral region, Spectroscopic properties, Transmission spectra, Upconversion luminescence, Zhang.
Abstract
Enhanced luminescence in rare‐earth‐doped chalcogenide glass–ceramics is of great interest for the potential integrated optoelectronic devices. However, fundamental mechanism on the enhancement of luminescence upon crystallization remains largely unknown. We report the fabrication and characterization of wide transmission chalcogenide glass and glass–ceramics based on the 25GeS2·35Ga2S3·40CsCl:0.3Er glass composition, and discuss the mechanism of enhanced luminescence. By monitoring the 4I9/2–4I15/2 of Er3+ transition, up‐conversion luminescence of 12 times higher was observed in glass–ceramics compared with that in base glass. Electron paramagnetic resonance (EPR) and Raman scattering spectroscopies were employed to obtain the information of selective environment of Er3+ ions and microstructural evolution with the crystallization progress. Both of them evidenced that the enhanced up‐conversion luminescence was mainly related to the local environmental evolution from a mixed chlorine‐sulfur coordination to a low phonon energy chlorine coordination in the residual glassy matrix of glass–ceramics.
Url:
DOI: 10.1111/jace.12102
Affiliations:
- France, République populaire de Chine
- Auvergne-Rhône-Alpes, Rhône-Alpes, Région Bretagne
- Rennes, Villeurbanne
- Université de Rennes 1
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Le document en format XML
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<front><div type="abstract">Enhanced luminescence in rare‐earth‐doped chalcogenide glass–ceramics is of great interest for the potential integrated optoelectronic devices. However, fundamental mechanism on the enhancement of luminescence upon crystallization remains largely unknown. We report the fabrication and characterization of wide transmission chalcogenide glass and glass–ceramics based on the 25GeS2·35Ga2S3·40CsCl:0.3Er glass composition, and discuss the mechanism of enhanced luminescence. By monitoring the 4I9/2–4I15/2 of Er3+ transition, up‐conversion luminescence of 12 times higher was observed in glass–ceramics compared with that in base glass. Electron paramagnetic resonance (EPR) and Raman scattering spectroscopies were employed to obtain the information of selective environment of Er3+ ions and microstructural evolution with the crystallization progress. Both of them evidenced that the enhanced up‐conversion luminescence was mainly related to the local environmental evolution from a mixed chlorine‐sulfur coordination to a low phonon energy chlorine coordination in the residual glassy matrix of glass–ceramics.</div>
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